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Just google my screen name, two reef tanks and three FW south american biotope tanks.
4MOREWARS has provided you with some very good advice. Heed all of it like it was the gospel. I'm glad that you've decided to start with a larger tank, as the more volume of water you have to play with, the easier it is for the tank to absorb some of your rookie mistakes. Everybody makes mistakes, i've been keeping tanks for 25 years and I still make them occasionally.
There are so many tips. Where do I begin?
Go with a fully submersable heater at 5 watts per gallon, such as a visi therm or ebo jaeger unit. Also, remember to unplug it during water changes as they can shatter if exposed to air.
My advice, as a first timer, would be to go with artificial decorations instead of live plants. Most tank setups out of the box don't have the right kind of lights, nor the right spectrum and intensity, for live plants. Don't worry, there are plenty of artificial plant options, and don't skimp. Fish like places to hide behind. Remember, big fish will often redecorate your tank for you whether you like it or not. Oscars are famous for this. Untreated driftwood is often a hazard to new tanks, so go with artificial driftwood if you can find it. Caves, cliffs and ceramic objects are just fine. Do not use shells, rocks containing calcium (unless sw or african cichlid setup) or metal of any type as a decoration.
Think about the fish you'd like to keep first before mixing and matching. Different tropical fish come from different parts of the world and prefer different water conditions. For example, South American Cichlids perfer soft water with an acidic pH, so you'll want to re-create that for your tank. Whereas African Cichlids perfer hard water and an alkaline pH.
Invest in a good test kit, such as a FW master test kit, so you can always keep an eye on pH, hardness and nitrogenous waste problems. A good test kit will let you know when your tank has completely cycled and is ready for more fish.
I use a python-no-spill system for my freshwater tanks and it's very convenient to use. You hook it up to any threaded 3/4" tap in your house (such as your kitchen sink) and you can fill and drain your tank without having to haul buckets of water around. They come in 50 foot and 100 foot versions and looks like a regular gravel vaccume hooked up to a clear hose. Just add dechlorinator to your tank when you fill, and go.
Understanding the nitrogen cycle is the most crucial aspect of fishkeeping, and diciplining yourself to do partial water changes on a weekly basis. If you can do that, you'll have a successful tank. Do not rush new tank syndrome, and do not rely on off the shelf "cycling" products. It takes time and patience. Add your goldfish or black mollies when you first set up the tank and don't remove them until the tank has cycled (ammonia zero, nitrite zero).
Remeber, there are 3 types of filtration: Mechanical, chemical and biological. The most efficient for a fw tank is a wet/dry unit with a mechanical filter and carbon chamber. Cannister filters are very good for big tanks but are a PITA to service. You need about ten tank volumes per hour going through your filter system. So, at 125 gallons, you need 1,250 gph of flow. If you can afford it, go with a wet/dry setup with a sump underneath the tank (in the tank stand) or an integrated 125 tank with wet/dry (wet dry built in on back).
Acrylic tanks scratch easily so be careful of this. Make sure that when you install and set up your tank, you use a carpenter's level to make sure the tank is perfectly level on the ground. If it's slightly off in one corner, it will crack with a stress fracture.
This is a typical ticking timebomb: The typical particle board tank stands will warp within five years. Constant exposure to water and humidity, combined with the weight of the tank, will cause the stand to warp and will cause a glass tank to stress fracture. On big tanks, I usually remove any laminate and seal the bare wood with thompson's water seal, then paint the stand inside and out with a good marine quality paint. This will seal the tank stand and prevent warping. You can buy marine paint at any boat supply company. That, or go with a metal frame stand (paint with rustoleum first) or alternative material, such as brick or cinder block.
There's so much to go over, but you'll just have to learn as you go like we all have.
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