http://www.scientificamerican.com/article.cfm?id=smokestash-industry-arpa-e-seeks-carbon-capture-breakthroughs March 9, 2010 | 4 comments
Smokestash Industry: ARPA-E Seeks Breakthroughs in Carbon Capture Technology
Humans can capture and release CO2 efficiently, so why can't power plants?
By David Biello
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Research engineer Harry Cordatos and his colleagues at United Technologies Corp. (UTC) are working on just such a system—and have garnered funding from the U.S. Department of Energy's new ARPA-E program. After all, UTC subsidiary Hamilton Sundstrand has been making CO2 capture units for the space program since the 1960s with different technology. But carbonic anhydrase "captures 600 molecules every second," Cordatos said at the ARPA-E summit in Washington, D.C., last week. "To take this enzyme out of the body is challenging. Our bodies continuously regenerate the enzyme because it degrades."
So Cordatos and UTC's idea is not to use the enzyme itself, but to master its chemistry and "use it in the unnatural environment of power plant flue gas," Cordatos said. The key appears to be a single zinc atom that sits at the core of the enzyme, which resembles a pyramid in structure. That structure allows the carbonic anhydrase to grip the CO2 "not too loose and not too tight," Cordatos explained, which is critical for efficiently capturing and then releasing the greenhouse gas.
UTC is not alone in this pursuit. In the ARPA-E program alone, four of the 37 funded developing technologies concerned researching more energy-efficient ways to capture the CO2 in a fossil fuel–fired power plant's flue gas. Chemist David Moore at Lehigh University in Bethlehem, Pa., employs electricity itself to charge absorbent materials for CO2 capture. Nalco Co., is developing an "electrochemical platform" to do the job. And physicist Olgica Bakajin of Hayward, Calif.–based Porifera, Inc., plans to use membranes composed of carbon nanotubes to separate CO2 from the other gases—using carbon to capture carbon.
"We need to develop the technologies that enable us to use our fossil fuels in a clean way," Secretary of Energy Steven Chu told ScientificAmerican.com at the conference. "This is something you don't solve in five years, 10 years. It will take a half century to get our carbon emissions down to where we need to go to protect the climate." At the same time, the U.S. will require a steady supply of electricity which, today, means coal burning or nuclear power, Chu said.
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