|
Edited on Sat Jul-16-05 08:11 PM by NNadir
I'll try to put it in simpler, if long winded, terms:
Polymers are giant molecules made from smaller subunits called monomers. Polyethylene for instance is a huge molecule that is a chain of a smaller (a two carbon molecule called ethene or "ethylene") discrete molecule.
Polymers are not limited to plastics made by human beings. Many living systems have polymers. An important class of such polymers are chains of small six carbon sugars.
The formation of these sugar polymers involves the removal of a water molecule. It is sometimes called "dehydration." The breaking down of sugar (and many other biological) polymers involves the addition of water molecules. It is commonly called "hydrolysis," literally "water breaking." Inside cells, hydrolysis and dehydration are effected with the use of very specific catalysts of relatively precise shapes. These are called enzymes.
There three main types of polymers of the most common sugar in living systems, glucose. These are cellulose, starch, and glycogen. The latter two are energy storage media in respectively, plants and animals. Because they are energy storage media, it is essential that plants and animals each have common enzymes that switch between the monomeric form, glucose, and the polymeric form. Such enzymes are widely distributed among almost all living things.
The difference between cellulose, starch and glycogen arise not from a difference in the monomers but in how the monomers are linked. Glucose is a three dimensional molecule: It has a "top," a "bottom" and "sides" that all differ. Plus there are different positions where the linkages can take place. There are in fact, many possible different types of polymers of glucose, but the most prominently found ones in nature are those which I have described.
Cellulose, although it requires the investment of energy to make, and thus contains (potential) energy is not primarily made cellular energy transactions. It is, instead, mainly used as a structural material which comprises wood and straw to give two examples. (The difference between wood an straw largely consist of the types and presence or absence of other types of polymers, called lignins - but all plant cell walls contain cellulose.) Enzymes that can break cellulose back into its constituent monomer, glucose, are relatively rare. In general they are only found in bacteria. In fact, in order to digest grasses, which are cellulose, the stomaches of solidungates (including horses and cows) must contain bacteria. If these bacteria die, the animal will die.
Enzymes work, in many cases, by behaving like acids. One definition of an "acid" is something that donates hydrogen ions (protons) to a molecule, causing it to insert water and hydrolyze.
Thus a brute force approach to hydrolysis of cellulose is to simply add acids, like sulfuric acid, or hydrochloric acid to wood or straw and to break it into simple sugar than can be fermented to give ethanol. With a little heat and time, this often actually works.
However, as mentioned in the paper, the simple addition of acids have drawbacks. The chief one is that they are corrosive, but another is that they represent a disposal - and therefore an environmental - problem. They must often be neutralized.
It would be nice if one could easily remove and add acids without much neutralization and separation. For many years this was not possible. But in the 1940's and 1950's chemists invented a form of insoluble acid that are known as ion exchange resins. These acids are different in that the acid molecule is itself bonded directly to a polymer, typically polystyrene. Thus instead of expensive processes like neutralization or extraction, the acid can be added and or removed simply by passing the solution over a solid material and then filtering it when desired. Such processes are superior in general because they can be made continuous. Continuous processes are always industrially cheaper than batch processes. Note that all current means of biological production of ethanol are batch processes. The manufacture of ethanol from ethene (from fossil fuel sources) is much cheaper (ignoring the external cost of global climate change) than biological methods in part because the fossil fuel process is continuous.
This is the basic idea of this paper.
Interestingly, ion exchange resins are very useful for recovering trace elements like those you mention, including potassium. In fact, many people have ion exchange resins in their home that remove calcium from their water: These are "water softener" systems. In theory ordinary water softeners could be used to "recover" calcium, if for some reason people had a need for it.
Such systems are more typically used for the removable of undesirable atoms, like lead or calcium, but they can also be used for recovery of desirable elements. The Japanese have, for instance, demonstrated an industrially scalable system for recovery of uranium from sea water using ion exchange. This process will only be economical, however, if the price of uranium rises to more than $200/kg, a factor of five higher than the current price.
Whatever the case, the paper describes of laboratory investigation. It is research, not commercial development. Whether it is useful, scalable, or economic remains to be seen. There are many unanswered and probably uninvestigated questions. It may be economic under some conditions and not others. There may be problems that prevent it from working on a scale greater than bench top. In general ion exchange resins are relatively expensive, although prices definitely are coming down. Ion exchange resins, unlike other types of acid, are reusable. They can function for many, many years with simple recharging processes.
I hope this clarifies the issues. Thanks for asking.
|