was dropped into the river, cracking. Over 100 gallons were released to the waterway.
This may not sound like much, until you account for the very low solubility of PCB and related chlorocarbons. Here is a table giving the total solubility for various chlorinated biphenyls:
http://wlapwww.gov.bc.ca/wat/wq/BCguidelines/pcbs/pcbs-02.htmAccording to this site,
http://www.chem.unep.ch/pops/POPs_Inc/proceedings/bangkok/FIEDLER1.html the density of PCB's range between 1.182-1.566 g/ml.
If we take the density value as 1.2 and recall that a gallon contains 3785.6 ml, and we take a PCB with a solubility of 10 micrograms per ml, we see that 1 gallon of PCB, weighing about 4.5 kg, is enough to saturate 450 million liters of water (120 million gallons). However, it is not this simple. Some of the PCB is undoubtedly extracted into hydrophobic pockets in the environment, some of which are represented by oily plants and oily plankton. Thus it is not immediately released into the flowing water but can persist for long periods of time, and be concentrated by the food chain.
(A similar situation is obtained for tetrachloroetheylene (TCE), aka dry cleaning fluid. A few gallons can contaminate a large volume of water for years. As TCE was widely used to degrease autoparts in gas stations, about 30% of the groundwater in the United States contains measurable concentrations. The well at my home frequently exceeds the action level, about 1 ppb. I have remediated it with a carbon filter which happily, also removes radon.)
It also appears that the PCB contamination was not limited to this single event, though the event was certainly regarded important enough to require years of clean up efforts.
Apparently a local company was collecting waste oil from City Light, a local power company and processing it near the river. Any waste oil from a power company was likely to contain PCB's for the simple reason that the most widespread use for PCB's was in transformers. (There are many, many existing transformers distributed around the country that still have PCB's in them: Transformers usually last a long time.)
This situation is described in this link:
http://seattlepi.nwsource.com/local/232345_duwamish13.html?searchpagefrom=1&searchdiff=0The Duwamish river is considered a superfund site.