A large amount of sewage sludge is produced in the world every year. In China, the total production of sewage sludge was up to 450 000 000 tons in 2003.1 The problem of how to deal
with the sludge is one of the most serious environmental issues...
...A technical guideline for the handling and disposal of urban waste released in 1992 in Germany3 requires that the organic content of any material deposited in landfill sites must be less than 5% from 2005, which obviously indicates that only incineration slag or ash is suitable for landfilling. Therefore, it is anticipated that incineration will be increasingly used...
However, incineration has obvious shortcomings, such as the emission of dioxins and heavy metals. In particular, the concentration of heavy metals in sewage sludge is critically high and the emission standards for toxic metals during sewage sludge incineration are now stricter than before. Thus, a study on how to control and reduce the emission of toxic metals during incineration is extremely urgent. Up to now, much research into the behavior and transformation of heavy metals during thermal processes has been conducted.3-11 However, this research only concentrated on how to stabilize or reduce the emission of heavy metals, primarily using sorbents.12-15 Few studies have considered the separation of heavy and alkali metals in the flue gas, especially the reuse and recycling of metals during waste thermal processes. As mentioned above, the concentrations of several heavy metals (Pb, Cu, and Zn) are very high in sewage sludge. Heavy metals can account for approximately 0.5-2.0% and in some cases even up to 4% of the total dry weight...16-19
In the ASAP section of
Energy and Fuels. Abstract is here:
http://pubs.acs.org/cgi-bin/abstract.cgi/enfuem/asap/abs/ef0501602.htmlA subscription is required for full access.
I am surprised at the mass of sewage sludge in China.
The sludge is said to have a calorific value approximately equal to that of brown coal, which is about 20,000 GJ/ton. If true, the amount of sewage sludge in China represents about 9 exajoules of primary energy.
China currently consumes about 50 exajoules of energy, most of it from coal.