I appreciate your opinions and the fact that you remain civil when expressing them.
Deadbroke says:
I'm not buying that the Trade Center only had 30 years of life, or that concrete was a culprit.
What I am saying about concrete is, in effect, dust to dust, ashes to ashes.
What I am saying is very controversial and there are many who do not support my iconoclastic views regarding cement and concrete.
But the trade mags appear to fully endorse my conclusions.
Sept. 12, 2001
"We know that concrete structures will eventually fail," said Krstulovic-Opara. "What we want to do is extend the length of time it takes for the structure to fail and control how it fails."
http://www.ncsu.edu/news/press_releases/01_09/247.htmSee what I mean?
So far I have NOT been PROVED wrong when I say that the CONCRETE is perishable.
February 1, 2004
There have been great advances in the understanding of concrete durability, especially in severe environments, yet durability still remains the foremost problem facing the industry today. We have only to look on our newly repaired bridges, parking structures, and buildings to see that we do not yet have adequate solutions; spalling, cracking, rust staining, and corrosion of reinforcing steel are visible problems. But behind these visible manifestations of concrete repair durability problems are more complex, invisible problems. This article will attempt to address some of these invisible problems in detail, namely the problems associated with applying experimental results to field conditions.
http://www.concreteinternational.com/pages/featured_article.asp?ID=12976 See what happens when Penta-concrete is exposed to DAILY temperature changes.
In the first 24 hours after the attack, structural engineers noticed the structure of Wedge One had shifted about 1/4 in. That measurement has since increased to about 1 in., officials say. But Lee Evey, program manager of the Pentagon Renovation Office, says the movement, along an expansion joint, could be an "old movement." Construction crews are noticing "micro fractures in the concrete," says Fontana.
Allyn Kilshimer, president of KCE Structural Engineers, Washington, D.C., says the cracks in the concrete and historic limestone facade are more the result from the drop in temperature in the evening and early morning hours, and that the amount of demolition work to be done has not changed. The temperature in Washington, D.C. had a 20-25°F change during the first few days in October. Kilshimer's firm was hired by Pentagon renovation officials to provide structural engineering oversite.
http://www.construction.com/NewsCenter/Headlines/ENR/20011009a.asp And this next article will give you a clue as to the type of cement used in the Penta-concrete.
The corrosion and spalling on the Pentagon walls were caused by carbonation that occurs when carbon dioxide in the air penetrates into the concrete and reacts with hydroxides (such as calcium hydroxide) to form carbonates. While harmless to the concrete matrix, carbonation significantly lowers the alkalinity (pH) of the concrete. High alkalinity is needed to protect embedded steel from corrosion; consequently, corrosion will set in if carbonation of the concrete occurs.
http://concreteproducts.com/ar/concrete_equipment_products_21/ Now take a look at the manner in which the Penta-concrete was installed when the Wedge was rebuilt after September 11.
How long do you suppose that concrete is going to last?
Testing the concrete slabs every few days, crews found the compressive strength had reached between 75 and 85% by day 14, says Kilsheimer. Because the project is on such a compressed schedule, workers are removing the shoring from formwork supplied by PERI Formwork Systems Inc., Hanover, Md., ahead of the typical 28-day curing schedule. Still, says Colsten, "safety is paramount when considering how to get work done while the concrete structure is still a green structure."
Kilsheimer says that it is not unusual to reach "at least 75% of the compressive strength" on day 14. But it is unusual to strip the formwork at that time, he says. Crews first remove the shoring, followed by the formwork. They then install a limited number of vertical aluminum reshores at a much wider spacing—about 11 ft on center instead of 2 or 3 ft. That allows electrical equipment to be installed about one month ahead of schedule, says Kilsheimer. The sequence is "almost never done," even in an expedited situation, according to Kilsheimer. He says it will also be used to install mechanical systems.
The concrete standard for a facility like the Pentagon is 4,000 psi, but government officials note that the rebuilding effort has incorporated changes in reinforcing methods, resulting in a HIGHER STRENGTH CONCRETE. The U.S. Army Corps of Engineers suggested a series of methods to improve construction from a force protection and life safety perspective, but officials decline to discuss specifics.
http://enr.construction.com/projects/buildings/archives/020204.aspIt would apear that High Strength Concrete (HSC) was used in the the Phoenix Project. And what does NIST have to say about HSC?
December 1996.
A review is presented of experimental and analytical studies on the performance of concrete when exposed to short-term, rapid heating as in a fire. Emphasis is placed on concretes with high original compressive strengths, that is, high-strength concretes (HSC). The compiled test data revealed distinct difference in mechanical properties of HSC and normal strength concrete (NSC) in the range between room temperature and about 450 deg C. The differences decreased at temperature above 450 deg C. What is more important is that many test programs, but not all, reported that HSC experienced explosive spalling during the fire tests.
http://fire.nist.gov/bfrlpubs/build96/art075.htmlhttp://fire.nist.gov/bfrlpubs/build00/art104.htmlSo it seems that an ordinary fire will cause severe and extensive damage to that newly-rebuilt Wedge. Incidentally, I cook tater-tots at 400 degrees and my oven can go up to 500 degrees. The tater-tots have NEVER exploded, unlike that concrete.
Let us return to the article which provided the original quote.
One of the problems with conventional concrete is that during extreme structural stress, such as is experienced during explosions or an earthquake, it breaks apart in large chunks and separates from the steel rebars. The result is that large slabs and chunks of concrete fall from the structure, hurting the inhabitants and crushing anything beneath them.
Krstulovic-Opara has been developing the HPFRC system using fibre mats injected with a special concrete slurry, a mixture of concrete, aggregate and liquids. The mats are made of recycled stainless steel fibres and come in large rolls that can be cut and shaped to fit the space or use desired. The fibre mats add tensile strength and ductility energy-absorbing properties to the concrete.
http://www.hindu.com/thehindu/2001/09/20/stories/08200001.htmAs you know by now, concrete is porous and is susceptible to water damage.
When the concrete absorbs water, the stainless steel fibers will be come coated with moisture which will cause the steel fibers to rust.
If high alumina cement was used, this could create problems.
The thermite reaction, discovered by Goldschmidt, is also a displacement reaction, but here aluminum reduces iron. The reaction is Fe2O3 + 2Al ? 2Fe + Al2O3, which liberates a good deal of heat. The liquid metal produced is at about 2300°C, which is very hot. Powdered aluminum and rust in the approximate ratio of 1:3 are packed in a refractory crucible with a magnesium ribbon, or a powder of magnesium and barium peroxide, to ignite it. Either the red or black iron oxide can be used, giving "red Thermit" or "black Thermit." A trade name for the powder is Thermit. The vigorous reaction makes liquid iron or steel, which flows out of a hole in the bottom of the crucible into the mold and can be used for welding. The stock to be welded is usually preheated with a gas flame playing through the mold. The metal produced is about half the weight of the original mixture. This reaction is also called aluminothermic, and can be used for reduction of other metals, such as nickel, manganese or chromium.
http://www.du.edu/~jcalvert/phys/alumin.htmAluminum powders can be used in wide ranges of application. Aluminium flakes for the production of aerated light weight concrete are getting more and more important all over the world. Through hydrogen development in the alkaline state a pore structure is created, which results in high insulation and absorption properties at low densities.
Research and development in connection with production know-how and competent advice ensure a leading position in the ALC industry as well as for manufacturers of light and insulating plasters.
Manufacturers of civil explosives and the pyrotechnical industry make use of the high oxygen affinity level of aluminum for, among others, the production of slurries (safety explosives), fireworks and sparklers. The reduction potential of aluminum is used for various chemical processes in the chemical industry.
Primary fields of application of aluminum flakes are:
Building materials - aerated light weight concrete, plasters (insulating, light and sanitation plasters)
Pyrotechnics - fireworks, sparklers
Explosives - watergels, slurry explosives
Chemistry - titanium oxide, Aluminium phosphite
http://www.schlenk.de/pigmente/eng/aluflakes.ihtmlAnd now let us look at insulation and fireproofing.
Shotcrete is pneumatically applied portland cement mortar made with an intimate mixture of Norlite and either portland cement or LUMNITE CEMENT. The material is shot into place by means of compressed air. For fireproofing structural steel members, proportions shall be in the 1:4 range for cement/aggregate.
http://www.norliteagg.com/maps/other.htmWhile Portland cement is described throughout the world by the name Portland, HAC has a wide variety of names. In the UK it is known as High-Alumina Cement and Aluminous Cement. HAC also has a variety of trade names such as Ciment Fondu and Lightning Cement. Outside the UK it is known as Ciment Alumineux in France, LUMNITE in the USA and Tonerdezement or Tonerdeschmelzzement in Germany.
The HAC Problem
Within about 30 years serious faults had been found in a number of structures, and its use except by licence, was banned in France in 1943 and later in Germany. In 1973, the collapse of a precast, prestressed roof beams over a swimming pool in a London school led to its exclusion for structural purposes from British Standard codes of practice and deletion from the Building Research Establishment's recommendations for concrete to be placed in sulphate bearing soils and groundwaters.
http://www.eclipsescientific.co.uk/environmental/hac.htmlThere is much much more to learned about concrete
(concrete fracturing, concrete-eating bacteria, etc etc)
but I will not get into that right now.
Perhaps now you can see why we really ought to spend some time studying the cement and the concrete used in the manufacture of the entire WTC complex. Remember, some of the buildings there collapsed WITHOUT having been hit by anything.
Why did they do that?
Then, on Sept. 11, they were faced with something no one could imagine.
That morning, Merco/Obayashi had approximately 1,000 pounds of explosives loaded and scheduled to be shot in the afternoon.
Then the unthinkable happened in nearby Manhattan.
“We actually saw the planes hit the World Trade Center,” recalled Mike Mergentime, vice president, Merco Inc.
“Then we saw the towers collapse.” The impact of the tragedy was immediate.
“We already had security in place,” Mergentime said, “but, after the attack, we got armed U.S. marshals guarding the job site.” Authorities would not permit anyone to keep explosives on the site overnight, so the charges were exploded at 3:30 p.m. the afternoon of Sept. 11.
Understandably, nearby residents were shaken by the blasting, and the New Jersey State Police immediately were on the scene fearing it might be another terrorist attack.
http://www.concretepumpers.com/MagArticle.asp?ArticleID=237