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I went to the ultra-organic politically correct-type place to see if I could find an alternative to glyphosate, and was told that they use undiluted vinegar. Which, while admittedly more, uh, "organic" than glyphosate, is HIGHLY toxic and lasts way, way longer in the soil than glyphosate, and causes many more problems for germinating seedlings, etc. Not to mention totally horking up the soil Ph.
In my experience you have two choices:
One: The "mechanical" method. This involves dressing up in old clothing plus a virtual (and disposable) hazmat suit: cheap coverall of non-porous material, non-porous gloves, non-porous shoe covers, etc. Plus a full head mask/breather. Use all-metal tools. Use heavy-grade plastic bags. Dig out the offenders, and bag immediately. Seal the bags. Be sure you've got it ALL. Take a fresh bag and CAREFULLY remove the hazmat gear and put it in the bag. Use a cheap pair of disposable garden gloves to carry all the bags to a truck bed or car trunk lined with newspaper. Did I mention, have a bathrobe and a washable laundry bag waiting inside the back door? When you get the bags loaded, go inside and take off your inner clothing layer and stuff it in the bag. Go shower--a long shower, let the water run all over. Wash the clothes. Drive the bags to a landfill or hazardous waste site.
Repeat in about ten weeks after the next round of seeds or chopped-off and missed rootlets starts growing.
Two: The "politically incorrect" method. Get a generic glyphosate spray and load it up in a single-purpose sprayer (you'll only ever use the sprayer for glyphosate application.) Dress in heavy, washable gear, including gloves, and cover all skin area. Wear safety goggles and mask. Carefully spray all the poison ivy/oak leaf surfaces. Store the glyphosate & sprayer safely, shuck off the gear and wash, shower as above. At LEAST two full weeks later (three is better) gear up again, take a couple of heavy plastic bags and clear any bulky remnants. Seal the bags carefully and dispose of properly. They won't be as dangerous, since they will have long since stopped exuding the toxic oils, but there may be some remaining.
Periodically check for new growth and get it while it's small. If you get it while it's small it will just wilt and decompose in place and you don't have to mess with it further.
Glyphosate breaks down very quickly (that is, the non-"extended" vareity does, which is what the generics are,) and is not immediately toxic to animal/human metabolism in small amounts. However, it is very toxic to non-woody plant growth so spray only on still days or in areas where blown/spread spray can't harm other plants.
I use glyphosate only for poison oak/ivy, witchweed, well-established bindweed, wiregrass, and a few other really horrid scourges. But I do use it for those. It's more effective than trying to dig them out (since many of them will re-root from even tiny fragments left behind in the soil) and less dangerous to me (I'm very allergic) than trying to deal with "live" poisons by mechanical methods.
compromisingly, Bright
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