http://people.ccmr.cornell.edu/~plh2/group/glblwarm/GLBLWARM.HTMand Wikipedia...
http://en.wikipedia.org/wiki/Greenhouse_effectand ORNL...
http://cdiac.ornl.gov/pns/faq.htmlQ. Why do certain compounds, such as carbon dioxide, absorb and emit infrared energy?
A. Molecules can absorb and emit three kinds of energy: energy from the excitation of electrons, energy from rotational motion, and energy from vibrational motion. The first kind of energy is also exhibited by atoms, but the second and third are restricted to molecules. A molecule can rotate about its center of gravity (there are three mutually perpendicular axes through the center of gravity). Vibrational energy is gained and lost as the bonds between atoms, which may be thought of as springs, expand and contract and bend. The three kinds of energy are associated with different portions of the spectrum: electronic energy is typically in the visible and ultraviolet portions of the spectrum (for example, wavelength of 1 micrometer, vibrational energy in the near infrared and infrared (for example, wavelength of 3 micrometers), and rotational energy in the far infrared to microwave (for example, wavelength of 100 micrometers). The specific wavelength of absorption and emission depends on the type of bond and the type of group of atoms within a molecule. Thus, the stretching of the C-H bond in the CH2 and CH3 groups involves infrared energy with a wavelength of 3.3-3.4 micrometers. What makes certain gases, such as carbon dioxide, act as "greenhouse" gases is that they happen to have vibrational modes that absorb energy in the infrared wavelengths at which the earth radiates energy to space. In fact, the measured "peaks" of infrared absorbance are often broadened because of the overlap of several electronic, rotational, and vibrational energies from the several-to-many atoms and interatomic bonds in the molecules. (Information from "Basic Principles of Chemistry" by Harry B. Gray and Gilbert P. Haight, Jr., published 1967 by W. A. Benjamin, Inc., New York and Amsterdam)
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